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Development of a particulate emulsifier by mechanochemical treatment and application to the liquid–liquid extraction process

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A method to modify quartz particles to be a surface-active material by mechanochemical treatment was successfully developed. The obtained particles had sufficient properties for use as a particulate emulsifier. The particles prepared by mechanochemical treatment had a highly anisotropic surface, and the droplets emulsified by those particles were extremely large and stable because of their stonewall-like structure and high density. The obtained particulate emulsifier was applied to the liquid–liquid extraction process. Consequently it was clarified that the extraction rate increased 3.6 times according to the increase of interfacial area without reducing the mass transfer coefficient.

Affiliations: 1: Department of Mechanical System Engineering, Graduate School of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2201, Japan


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