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Reconsideration on the Hüttig adsorption equation including statistical-thermodynamical derivation

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The Hüttig-type adsorption equation has been derived statistical-thermodynamically on the basis of a different interpretation for higher layers over the monolayer in Hüttig's original model. The differences of an adphase structure for higher layers between BET and the Hüttig or Hüttig-type equations and their adaptability to experimental isotherms are described.

Affiliations: 1: Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University, 2753 Ishiicho, Utsunomiya-shi 321, Japan


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