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Palladium Species in Pd/H-Zsm-5 Zeolite Catalysts for Ch4-Scr

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The active state of palladium for NO reduction with methane (CH4-SCR) was investigated by comparing the catalytic activity of Pd/H-ZSM-5 with that ofPdO/SiO2. High catalytic activity for CH4-SCR was given by Pd/H-ZSM-5 in the temperature range of 300-500 °C. PdO/SiO2 catalyzed the reaction between NO2 and CH4 in the absence of oxygen, which retarded the reaction by consuming CH4 in combustion. CHa combustion occurred on either zeolite-supported or silica-supported catalyst, while NO preferentially retarded the combustion on Pd/H-ZSM-5. NO was found to be chemisorbed on the palladium sites in zeolite, while it was hardly chemisorbed on PdO/SiO2. NaCl titration showed that the palladium species in zeolite are Pd2+ cations content, on which NO is strongly chemisorbed resulting in high selectivity for CH4-SCR.

Affiliations: 1: Department of Applied Chemistry, Waseda University, 3-4-1, Okubo, Shinjuku, Tokyo 169-8555, JAPAN

10.1163/156856700X00084
/content/journals/10.1163/156856700x00084
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/content/journals/10.1163/156856700x00084
2000-01-01
2016-12-07

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