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Cinnamaldehyde Hydrogenation Using Ruthenium-Tin Catalyst Type

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Bimetallic ruthenium-tin catalysts were prepared using the sol-gel method and the method of carrier impregnation. Two different procedures were used for their reduction - reduction in hydrogen atmosphere under an increased temperature, and reduction using an aqueous solution of sodium borohydride. Hydrogenation of 3-phenylpropenal (cinnamaldehyde) in tetrahydrofuran at 433 K and the total pressure 7 MPa was used as the model reaction for comparing the catalytic properties of the prepared catalysts. It was demonstrated that a tin addition notably affected catalytic properties of ruthenium in the sense of a selectivity increment related to the production of an unsaturated alcohol.

Affiliations: 1: Department of Organic Technology, Institute of Chemical Technology, 166 28 Praha 6, CZECH REPUBLIC

10.1163/156856700X00291
/content/journals/10.1163/156856700x00291
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/content/journals/10.1163/156856700x00291
2000-01-01
2016-12-03

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