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Esr Studies of α-Hydro p-Substituted Phenyl Nitroxides and Correlation Analysis of Their Hfsc Values

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image of Research on Chemical Intermediates

Well-resolved ESR spectra of a series of a-hydro p-substituted phenyl nitroxides were obtained in the fast ET reactions of p-substituted anilines with perfluoroacyl peroxides in F 113 (CCl2FCClF2) solutions and one parameter (σ or σ') as well as dual-parameter (σ, σ') correlation analyses of their hyperfine splitting constants were conducted.

Affiliations: 1: Shanghai Institute of Organic Chemistry, 200032 Shanghai, CHINA; 2: Chemistry Department, Shanghai Jiao-Tong University, 200240 Shanghai, CHINA


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