Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Unexpected Intermediate 1-Phenyl-2-(4-Pyridyl)Ethanol Isolated From Benzaldehyde and 4-Picoline Condensation Reaction

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

The unexpected intermediate 1-phenyl-2-(4-pyridyl)ethanol or 4-[2-(1-hydroxy-1-phenyl)ethyl]pyridine was isolated from the condensation reaction of 4-methylpyridine with benzaldehyde to form the model compound 4-styrylpyridine in the absence of a condensing agent. Spectroscopic data (NMR, IR and UV-VIS) gave evidence that the isolated compound is actually the alcohol just before the dehydration which yields the double bond of the 4-styrylpyridine and the structure was confirmed by single-crystal x-ray analysis.. The isolation method from the reaction mixture was difficult at first, but now a 10 % yield has been obtained, not only in powder form but as crystals good enough for R-X structural analysis.

Affiliations: 1: Centro de Quimica, Instituto de Ciencias, Universidad Autonoma de Puebla, P.O. Box 1613, 72000, Puebla, Puebla, MÉXICO

10.1163/156856700X00804
/content/journals/10.1163/156856700x00804
dcterms_title,pub_keyword,dcterms_description,pub_author
10
5
Loading
Loading

Full text loading...

/content/journals/10.1163/156856700x00804
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/156856700x00804
Loading

Article metrics loading...

/content/journals/10.1163/156856700x00804
2017-08-20

Sign-in

Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation