Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Hydroxyl radical induced oxidation of 3-methoxy4-hydroxy cinnamic acid (ferulic acid)

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

Access this article

+ Tax (if applicable)
Add to Favorites
You must be logged in to use this functionality

image of Research on Chemical Intermediates

Hydroxyl radical reaction of 3-methoxy-4-hydroxy cinnamic acid (ferulic acid) produced the .OH-radical adducts. A part of these radical adducts undergo water elimination to finally yield phenoxyl radicals and the process was found to be base catalysed. Phenoxyl radical of ferulic acid was further identified by following its reaction with more specific oxidising radicals, e.g. azide (N3.) and Cl.-2 in the pH range from 2.5 to 9. The phenoxyl radicals produced by one-electron oxidation did not possess any pKa in this pH range. The one-electron reduction potential for the formation of the phenoxyl radical was determined after achieving electron transfer equilibrium between the two couples involving the phenoxyl radical/phenol and phenothiazine radical cation/phenothiazine. Scavenging ability of the phenol toward NO.2 radical was evaluated.

Affiliations: 1: Radiation Chemistry & Chemical Dynamics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085, India

10.1163/156856701104202165
/content/journals/10.1163/156856701104202165
dcterms_title,pub_keyword,dcterms_description,pub_author
6
3
Loading
Loading

Full text loading...

/content/journals/10.1163/156856701104202165
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/156856701104202165
Loading

Article metrics loading...

/content/journals/10.1163/156856701104202165
2001-07-01
2016-12-04

Sign-in

Can't access your account?
  • Tools

  • Add to Favorites
  • Printable version
  • Email this page
  • Subscribe to ToC alert
  • Get permissions
  • Recommend to your library

    You must fill out fields marked with: *

    Librarian details
    Your details
    Why are you recommending this title?
    Select reason:
     
    Research on Chemical Intermediates — Recommend this title to your library
  • Export citations
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation