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Spin trapping with phosphonothionesters. Part VI. * Phosphoryl- and thiophosphoryl-thionformates

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Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate, ethyl (diethoxyphosphoryl)thiolformate, and ethyl (diethoxythiophosphoryl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters; even the former compounds, however, exhibited a remarkably lower reactivity than similarly substituted dithioesters.

Affiliations: 1: ICoCEA, Area della Ricerca del CNR, Via P.Gobetti 101, I-40129 Bologna, Italy; 2: Laboratoire de Chimie Moléculaire et Thio-Organique (UMR 6507), ISMRA, 6 Bd Maréchal Juin, F-1450 Caen, France

10.1163/156856701317051752
/content/journals/10.1163/156856701317051752
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/content/journals/10.1163/156856701317051752
2001-09-01
2016-12-10

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