Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Electron transfer: 150. The reaction of corrin-bound cobalt(III) with indium(I) — an additional mechanistic variation

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

Access this article

+ Tax (if applicable)
Add to Favorites
You must be logged in to use this functionality

image of Research on Chemical Intermediates

(Corrin)cobalt(III) is reduced by indium(I) to its Co(II) counterpart (cob(II)alamin, B12r) at pH 1-2 in aqueous chloride. In these solutions the aqua oxidant (B12a) is in mobile anation equilibrium with its chloro derivative. At [Cl] ⩿ 0.03 M, consumption of Co(III) is exponential and proceeds by parallel paths involving the aqua- and chloro-substituted oxidants. At [Cl]  0.10 M, rates are governed mainly by an preliminary act requiring In(I) and 2 Cl, but no Co(III). This initiation step generates a more reactive In(I) species which is taken to result from a slow heterolysis and loss of ligating water from InCl2(aq).


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Tools

  • Add to Favorites
  • Printable version
  • Email this page
  • Subscribe to ToC alert
  • Get permissions
  • Recommend to your library

    You must fill out fields marked with: *

    Librarian details
    Your details
    Why are you recommending this title?
    Select reason:
    Research on Chemical Intermediates — Recommend this title to your library
  • Export citations
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation