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Photoluminescence study of mesoporous MCM-41 and Ti-grafted MCM-41

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Photoluminescence combined with diffuse reflectance UV–Vis spectroscopy was used to characterise both the pure siliceous MCM-41 and Ti-MCM-41 containing tetrahedral Ti(IV) species anchored onto the inner walls of the siliceous MCM-41. Both Ti-MCM-41 and MCM-41 showed complex photoemission signals and this study allows, for the first time, the distinction of the emission signals of tetrahedral Ti(IV) ions from those due to silica surface centres.


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