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Redox reactions of disulfiram: a pulse-radiolysis study

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Redox reactions of disulfiram (DSF) were studied in aqueous solutions using the pulse-radiolysis technique. Reactions of DSF with one-electron oxidants Br˙2- and N˙3, generated pulse radiolytically in aqueous solution at pH 7, yielded a transient (λmax = 480 nm) which exhibited the characteristics of a disulphide cation radical and decayed by second-order kinetics. Reactions of DSF with halogenated peroxyl radicals CCl32, CHCl22, CH2ClO˙2 and CBr32 led to the formation of an adduct absorbing at 580 nm. The reduction potential was estimated to be 1.24 ± 0.06 V vs. NHE.


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