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The intercalation of metalloporphyrin complex anions into layered double hydroxides

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Investigations to elucidate the structures of the cobalt(III) and manganese(III) complexes of tetra(p-sulfonatophenyl)porphinate anions (M(III)TSPP; M = Co and Mn), intercalated in Mg-Fe/Cl and Mg-Al/Cl layered double hydroxides (LDHs) have been carried out. Powder X-ray diffraction analysis, IR and UV-vis diffuse reflectance spectroscopy of Co(III)TSPP and Mn(III)TSPP intercalated into the interlayer spaces of LDH resulted in their perpendicular alignment against the host layers in the plane of the hybrid.

10.1163/156856703764929994
/content/journals/10.1163/156856703764929994
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/content/journals/10.1163/156856703764929994
2017-12-12

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