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Coal fly ash decomposes diethyl phthalate

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Decomposition of diethyl phthalate (DEP) exposed to a coal fly ash has been investigated in water by measuring UV-VIS spectra and GC-MS. Alkaline constituents eluted from the fly ash in the liquid phase gradually hydrolyzed DEP to produce monoethyl phthalate and/or phthalic acid. These products were adsorbed on the fly ash and decarboxylated into ethyl benzoate and benzoic acid, respectively, followed by decomposition into benzenes and/or the other compounds of lower molecular weight. The fly ash acts as not only an adsorbent but also a decomposer.

10.1163/156856703765694372
/content/journals/10.1163/156856703765694372
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/content/journals/10.1163/156856703765694372
2017-10-20

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