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Investigation on the properties of the transient absorption of cyclometallated Pt(II) complexes using picosecond and nanosecond laser-flash photolysis

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The transient species of the [ppbpy]Pt(II)R (ppbpy = 4-pyrene-6-phenyl-2,2′-bipyridine, Ph—C≡C (PyPPt), R=Cl (PyClPt)) complexes were investigated in solution by employing nanosecond and picosecond pump-probe spectroscopy. The interligand triplet state is found to be main intermediate. The growth of the triplet state is a fast process (< 10 ps), and the lifetime of transient decay is about 7μs, which is matched with the lifetime of luminescence.

10.1163/1568567041280881
/content/journals/10.1163/1568567041280881
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/content/journals/10.1163/1568567041280881
2017-11-25

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