Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Electron transfer (oxidation) of complexes between bifunctional phenols and DMSO in non-polar surroundings

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

Access this article

+ Tax (if applicable)
Add to Favorites
You must be logged in to use this functionality

image of Research on Chemical Intermediates

Pulse-radiolysis reactions were performed to study the effect of hydrogen bonding to dimethyl sulfoxide (DMSO) on the oxidation of dihydroxy benzene and biphenyl diols to phenoxyl radicals. It was observed that with DMSO as the hydrogen-bond acceptor, the oxidation process proceeds via proton-coupled electron transfer in the case of hydroquinone. For resorcinol, DMSO acts in a similar way as in the case of hydroquinone. For other biphenols, viz., 2,2′- and 4,4′-biphenyl diols, it was found that DMSO had no effect on the electron transfer. The results are explained based on the ionization potential and structure of the phenol derivatives which probably depends on the rotation of the OH bond causing different electron distribution in the transient conformation.

10.1163/1568567042420785
/content/journals/10.1163/1568567042420785
dcterms_title,pub_keyword,dcterms_description,pub_author
6
3
Loading
Loading

Full text loading...

/content/journals/10.1163/1568567042420785
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/1568567042420785
Loading

Article metrics loading...

/content/journals/10.1163/1568567042420785
2004-11-01
2016-12-07

Sign-in

Can't access your account?
  • Tools

  • Add to Favorites
  • Printable version
  • Email this page
  • Subscribe to ToC alert
  • Get permissions
  • Recommend to your library

    You must fill out fields marked with: *

    Librarian details
    Your details
    Why are you recommending this title?
    Select reason:
     
    Research on Chemical Intermediates — Recommend this title to your library
  • Export citations
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation