Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Ab initio investigation of the O–H insertion reactions of CH2X–X(X = Cl, Br, I) isopolyhalomethanes with water

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

Access this article

+ Tax (if applicable)
Add to Favorites
You must be logged in to use this functionality

image of Research on Chemical Intermediates

Here, we report ab initio calculations for the O–H insertion reactions of CH2X–X(X = Cl, Br, I) with H2O and examine substituent effects for changing the halogen atom. As Cl changes to Br and then I, the O–H insertion reactions lead to an HX acid leaving group and range from about 2.3 kcal/mol for X = Cl to about 16.3 kcal/mol for X = I. We compare the trends as the halogen atom varies from Cl to Br and I in the O–H insertion reactions of CH2X–X with H2O to the cyclopropanation reactions of CH2X–X with ethylene. We very briefly discuss possible implications for phase-dependent photochemistry of polyhalomethanes in the atmosphere.

10.1163/1568567054909104
/content/journals/10.1163/1568567054909104
dcterms_title,pub_keyword,dcterms_description,pub_author
6
3
Loading
Loading

Full text loading...

/content/journals/10.1163/1568567054909104
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/1568567054909104
Loading

Article metrics loading...

/content/journals/10.1163/1568567054909104
2005-09-01
2016-12-02

Sign-in

Can't access your account?
  • Tools

  • Add to Favorites
  • Printable version
  • Email this page
  • Subscribe to ToC alert
  • Get permissions
  • Recommend to your library

    You must fill out fields marked with: *

    Librarian details
    Your details
    Why are you recommending this title?
    Select reason:
     
    Research on Chemical Intermediates — Recommend this title to your library
  • Export citations
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation