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EPR studies of spin–spin interactions between Cu(II) centers in dimeric, hexameric and homo- and heteronuclear tetrameric complexes

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Applications of conventional (X-band), High-Field and High-Frequency EPR to study the nature of exchange interactions between Cu(II) centres in different homo- and hetronuclear systems are reviewed. The fine structure EPR spectra have been observed and analyzed in terms of spin-Hamiltonian parameters corresponding to S ≥ 1 for different [Cu2(β-alanine)4Cl2]Cl2·H2O dimeric complexes present in one unit cell, Cu(II) dimers possessing different conformations, dimeric species formed between Cu(II) ions and polyfunctional ligand in solution, Cu–Zn–Cu–Zn and Cu–Co–Cu–Co tetrameric heterometallomacrocycles, Cu4O4 cubane-like tetramers and for the chain Cu(II) hexamer.

Affiliations: 1: Faculty of Chemistry, University of Wroclaw, 14 Joliot-Curie Str., 50-383 Wroclaw, Poland; 2: Department of Inorganic Chemistry, National Taras Shevchenko University, Volodimirska str. 64, Kyiv 01033, Ukraine; 3: National High Magnetic Field Laboratory FSU, 1800 E. Paul Dirac Drive, Tallahassee, FL 32310-3706, USA

10.1163/156856707782169381
/content/journals/10.1163/156856707782169381
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/content/journals/10.1163/156856707782169381
2007-09-01
2016-12-04

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