Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

An environmentally benign route for epichlorohydrin from allyl chloride epoxidation catalyzed by heteropolyphosphatotungstate

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

In the absence of organic solvent, allyl chloride was epoxidized with aqueous hydrogen peroxide catalyzed by a heteropolyphosphatotungstate catalyst with very good activity and recycling activity. Under optimized conditions, an epichlorohydrin yield of 88.7% was achieved in the first run; after two recycles, the epichlorohydrin yield remained still above 85.0%. Various factors affecting the catalytic reaction were investigated systematically. The reaction rate of hydrogen peroxide in the epoxidation of allyl chloride is zero order with respect to hydrogen peroxide. The activation energy is 52.27 kJ/mol.

Affiliations: 1: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation