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ZnFe2O4 as a new catalyst in the C-methylation of phenol

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This paper reports the investigation of C-alkylation of phenol with methanol over zinc ferrite as a catalyst. The reactions were carried out in gas phase at atmospheric pressure in dependence of increasing temperature. The total selectivity towards ortho-cresol and 2,6-xylenol over 300°C surpassed 90%. ZnFe2O4 was obtained by oxidative precipitation method from solution of iron (II) sulphate and zinc sulphate at 60°C. Based on the results, the best equation describing the oxidation reaction rate was found. The obtained products have been investigated using X-ray fluorescence spectrometry and X-ray diffraction analysis.

Affiliations: 1: Institute of Chemistry and Environmental Protection, Szczecin University of Technology, al. Piastów 42, Szczecin 71-065, Poland; 2: W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, Wrocław 2, 50-950, Poland; 3: W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, Wrocław 2, 50-950, Poland;, Email: R.Klimkiewicz@int.pan.wroc.pl

10.1163/156856708783359478
/content/journals/10.1163/156856708783359478
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/content/journals/10.1163/156856708783359478
2008-01-01
2016-12-04

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