Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Reactions of reducing radicals with 2- and 3-nitroanilines in aqueous solutions: a pulse radiolysis study

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

Access this article

+ Tax (if applicable)
Add to Favorites
You must be logged in to use this functionality

image of Research on Chemical Intermediates

Reactions of 2- and 3-nitroanilines (2- and 3-NA) with eaq, H-atoms and one-electron reductants have been studied using pulse radiolysis in aqueous solutions. Reactions of eaq were found to be quite fast with both 2-NA and 3-NA resulting in their corresponding semi-reduced species which are reducing in nature. Reduction potentials for 2-NA/2-NA•− have been estimated to be approx. −0.56 V vs. NHE and that for 3-NA/3-NA•− was found to be between −0.185 V and −0.45 V vs. NHE. Semi-reduced 2-NA has main absorption peak at 300 nm with a shoulder in the 350 nm region and a broad weak band in the 470–500 nm region, whereas semi-reduced 3-NA possesses an absorption peak at 520 nm. Reducing radicals such as (CH3)2COH and CO2•− reacted with 2-NA, producing semi-reduced species, whereas reactions of these radicals with 3-NA produced their corresponding radical-adduct species.

Affiliations: 1: Water and Steam Chemistry Division, Kalpakkam, Tamil Nadu-603102, India; 2: Radiation and Photochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India; 3: Radiation and Photochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India;, Email:


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Tools

  • Add to Favorites
  • Printable version
  • Email this page
  • Subscribe to ToC alert
  • Get permissions
  • Recommend to your library

    You must fill out fields marked with: *

    Librarian details
    Your details
    Why are you recommending this title?
    Select reason:
    Research on Chemical Intermediates — Recommend this title to your library
  • Export citations
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation