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Selective oxidation of n-butane over Fe-promoted vanadyl pyrophosphate prepared from modification of nano-sized interlayer of lamellar vanadyl benzylphosphate

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A novel approach for the preparation of promoted vanadyl pyrophosphate in well-defined structure was examined. Lamellar vanadyl benzylphosphate (LVBP) was used as a host material and iron acetylacetonate as a guest. It was found that iron acetylacetonate was successfully inserted into the interlayer of LVBP by heating of LVBP and iron acetylacetonate in toluene solution. Calcination of this intercalated material resulted in a well-crystallized vanadyl pyrophosphate phase with uniform dispersion of Fe in bulk and surface. The obtained Fe-promoted vanadyl pyrophosphate showed an enhancement in the activity for selective oxidation of n-butane, especially at high temperature and long contact time.

Affiliations: 1: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan; Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute, GB Marg, Bhavnagar-364002, India; 2: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan; 3: Graduate School of Environmental Earth Science, Hokkaido University, Sapporo 060-0810, Japan


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