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Effect of benzothiophene on tetralin hydrogenation over supported rhodium catalyst in supercritical carbon dioxide solvent

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image of Research on Chemical Intermediates

The hydrogenation behavior of tetralin in the presence and absence of benzothiophene was studied over a charcoal-supported rhodium catalyst in supercritical carbon dioxide solvent. The catalyst activity, as well as cis-decalin selectivity, decreased in the presence of benzothiophene.

Affiliations: 1: Research Center for Compact Chemical Process, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1, Nigatake, Miyagino, Sendai, 983-8551, Japan


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