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Microstructure analysis of ethylene/1-hexene co-polymers with embedded rac-Et[Ind]2ZrCl2 metallocene catalyst

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Co-polymerization of ethylene and 1-hexene using rac-Et[Ind]2ZrCl2/MAO catalyst embedded in polystyrene in liquid slurry process was examined. The embedded catalyst was prepared by polymerizing a small amount of styrene. The specific activities and bulk densities of the copolymers produced by the embedded catalyst were higher than those of the homogeneous catalyst. The produced co-polymer with embedded catalyst had more random distribution of 1-hexene at the similar co-monomer content than that with homogeneous catalyst.

Affiliations: 1: School of Chemical Engineering and Bioengineering, University of Ulsan, Ulsan 680-749, Korea; 2: School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea


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