Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

How Is 1,1-Dimethyl-1-Silacyclopent-2-Ene Formed in the Addition of Dimethylsilylene To 1,3-Butadiene? Evidence for a Pathway Via a Vinylsilirane Intermediate

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

Addition of dimethylsilylene Me2Si: to 1,4-dideutero-1,3-butadiene in gas-phase flow pyrolysis experiments leads to the formation of 2,5-dideutero-1,1-dimethyl-1-silacyclopent-3-ene and 4,5- dideutero-1,1-dimethyl-1-silacyclopent-2-ene. Pyrolysis of the silacyclopent-3-ene product leads to the same silacyclopent-2-ene. This labelling pattern for the silacyclo-pent-2-ene product is compelling evidence for its formation via carbon-carbon bond-cleavage in a vinylsilirane intermediate, and for the intermediacy of the vinylailirane in the silylene addition leading to the silacyclopent-3-ene as well.

Affiliations: 1: Department of Chemistry Washington University Saint Louis, Missouri 63130 U.S.A.


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation