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Dichlorosilylene: Rate Constant for the Gas-Phase Reaction With Nitric Oxide

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Using the recently detected intense UV absorption spectrum of SiCl2(X1A1) it has been established that SiCl2 reacts with nitric oxide in the gas phase with a bimolecular rate constant, k(SiCl2 + NO), of (1.6 ± 0.1) × 109 M-1s-1 at 25° C.

Affiliations: 1: Department of Chemistry University of Alberta Edmonton, Alberta, Canada T6G 2G2; 2: Department of Chemistry Simon Fraser University Burnaby, British Columbia, Canada V5A 1S6


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