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Dichlorosilylene: Rate Constant for Reaction With Carbon Monoxide and Nitrous Oxide

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The absolute rate constants for the gas-phase reactions of 1,1-dichlorosilylene with carbon monoxide and nitrous oxide have been determined using the flash photolysis-kinetic absorption spectroscopy technique. The bimolecular rate constant values at 25° C are: k(Cl2Si+CO) (6.3 ± 0.7) x 108 M-1s-1 k(Cl2Si+N20) = (5.7±0.3) × 108M-1s-1

Affiliations: 1: Department of Chemistry University of Alberta Edmonton, Alberta, Canada T6G 2G2; 2: Chemistry Department Simon Fraser University Burnaby, B.C., Canada V5A 1S6


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