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Laser Photolysis of Polymer Eda Complexes Including 4,4'-Diaminodiphenylmethane Derivatives

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image of Research on Chemical Intermediates

Transient optical absorption spectra were obtained and photochemical transformations of aromatic amine derivatives (Am) used as electron donors in polymer EDA complexes were studied. It was shown that successive electron - proton - electron processes in (Am.CBr4) complexes are strongly influenced by whether the Am is monomer or a molecular fragment chemically incorporated into a macromolecular chain.

Affiliations: 1: A.N. Frumkin Institute of Electrochemistry of the Academy of Sciences of the USSR 117071 Moscow V71, Leninsky Prospekt 31, U.S.S.R.; 2: Sektion Chemie der Friedrich-Schiller-Universität Jena 6900 Jena Humboldtstrasse, G.D.R.


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