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Laser Photolysis of Polymer Eda Complexes Including 4,4'-Diaminodiphenylmethane Derivatives

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Transient optical absorption spectra were obtained and photochemical transformations of aromatic amine derivatives (Am) used as electron donors in polymer EDA complexes were studied. It was shown that successive electron - proton - electron processes in (Am.CBr4) complexes are strongly influenced by whether the Am is monomer or a molecular fragment chemically incorporated into a macromolecular chain.

Affiliations: 1: A.N. Frumkin Institute of Electrochemistry of the Academy of Sciences of the USSR 117071 Moscow V71, Leninsky Prospekt 31, U.S.S.R.; 2: Sektion Chemie der Friedrich-Schiller-Universität Jena 6900 Jena Humboldtstrasse, G.D.R.


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