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Dibromosilylene: Determination of the Absolute Rate Constants for Its Gas-Phase Reactions With Oxygen and Nitric Oxide

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Following the newly- discovered UV absorption spectrum of Br2Si, its reactions with oxygen and nitric oxide in the gas phase have been quantitatively investigated using the flash photolysis-kinetic absorption spectroscopy technique. The room temperature bimolecular rate constants are:

Affiliations: 1: Chemistry Department University of Alberta Edmonton, Alberta Canada T6G 2G2; 2: Chemistry Department Simon Fraser University Burnaby, British Columbia, Canada V5A 1S6


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