Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Photoluminescence and Ft-Ir Studies of the Dissociative Adsorption of H2 On the Active ZrO2 Catalyst and Its Role in the Hydrogenation of Co

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

Access this article

+ Tax (if applicable)
Add to Favorites
You must be logged in to use this functionality

image of Research on Chemical Intermediates

Photoluminescence and FT-IR studies of the adsorption of H2 on ZrO2 catalysts have been performed to clarify the true nature of active surface sites for the activation of H2 in connection with the CO - H2 reaction on the catalyst. The results indicate that the coordinatively unsaturated surface sites with different coordination numbers are generated on the surfaces by evacuation at temperatures higher than 600 K. These surface sites of lower coordination play a significant role in the reversible and irreversible dissociative adsorption of H2 on the active ZrO2 catalyst. The former seems to act as active hydrogen species for the CO - H2 reaction to form branched hydrocarbons on the ZrO2 catalyst.

Affiliations: 1: Department of Applied Chemistry University of Osaka Prefecture Mozu-Umemachi 4-804 Sakai, Osaka 591, Japan; 2: Research Laboratory of Resources Utilization Tokyo Institute of Technology Nagatsuta, Midori-ku Yokohama 227, Japan

10.1163/156856790X00085
/content/journals/10.1163/156856790x00085
dcterms_title,pub_keyword,dcterms_description,pub_author
6
3
Loading
Loading

Full text loading...

/content/journals/10.1163/156856790x00085
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/156856790x00085
Loading

Article metrics loading...

/content/journals/10.1163/156856790x00085
1990-01-01
2016-12-07

Sign-in

Can't access your account?
  • Tools

  • Add to Favorites
  • Printable version
  • Email this page
  • Subscribe to ToC alert
  • Get permissions
  • Recommend to your library

    You must fill out fields marked with: *

    Librarian details
    Your details
    Why are you recommending this title?
    Select reason:
     
    Research on Chemical Intermediates — Recommend this title to your library
  • Export citations
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation