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Photolysis of Tris(Trimethylsilyl)-Phenylsilane in Alcohols: a Consecutive Generation of Sililene Species

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Photolysis of tris(trimethylsilyl)phenylsilane, in alcohols yielded 1-alkoxy-1-phenyl-2,2,2-trimethyldisilane, dialkoxyphenylsilane, hexamethyldisilane, and trimethylsilane as major products. The formation of the products was explained by a mechanism which included the consecutive generation of phenyltrimethylsilylsilylenes and alkoxyphenylsilylenes.

Affiliations: 1: Osaka Prefectural Radiation Research Institute 174-16 Shinke-cho, Sakai, Osaka 593, Japan


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