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Rate Constants for Silylene Reactions

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It is only since 1985 that the absolute rate constants have been measured for some reactions of divalent silylene species. In this article the absolute rate constant data reported to date for the reactions of SiH2, SiMe2, SiMePh, SiHCl, SiCl2, SiF2 and SiBr2 are reviewed and, where possible, mechanistic pathways discussed. The reactivity of silylenes is, in general, much higher than had previously been estimated on the basis of relative rate studies.

Affiliations: 1: Department of Chemistry University of Alberta Edmonton, Alberta, Canada T6G 2G2; 2: Department of Chemistry University of California Irvine, California 92664, USA; 3: Department of Chemistry Simon Fraser University Burnaby, British Columbia, Canada V5A 1S6


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