Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

The Electron Spin Polarized (Cidep) Spectrum of the Propan-2-Olyl Radical

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

It is demonstrated that the origin of the absorptive contribution observed in the spin polarized esr spectrum of the propan-2-olyl radical when it is created by flash-photolysis of propan-2-one (acetone) in a hydrogen-donating solvent is not the triplet mechanism of CIDEP, as previously assumed. It is shown to arise not in the photochemistry or photophysics of the parent molecule, but rather to be a property of the radical pair itself. Arguments are presented to demonstrate that its origins may lie in an unidentified novel polarization process, rather than the possible redistribution of level populations via very fast relaxation processes.

Affiliations: 1: Physical Chemistry Laboratory South Parks Road Oxford OX1 3QZ UK

10.1163/156856791X00228
/content/journals/10.1163/156856791x00228
dcterms_title,pub_keyword,dcterms_description,pub_author
10
5
Loading
Loading

Full text loading...

/content/journals/10.1163/156856791x00228
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/156856791x00228
Loading

Article metrics loading...

/content/journals/10.1163/156856791x00228
2017-08-20

Sign-in

Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation