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Cage Effect in the Cidep Observation of the Photolysis of the Pyruvic-Lactic Acid System

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Strong intermolecular interactions in pyruvic acid/lactic acid solutions result in the observation of several unusual effects in the CIDEP spectra detected after photolysis. These effects are discussed in terms of a free diffusion model and a cage model of the radical pair mechanism of CIDEP.

Affiliations: 1: Department of Chemistry Queen's University Kingston, CANADA K7L 3N6

10.1163/156856791X00237
/content/journals/10.1163/156856791x00237
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/content/journals/10.1163/156856791x00237
2017-12-14

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