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Nanometer Particles Synthesis in Reverse Micelles: Influence of the Size and the Surface On the Reactivity

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In this paper we are presenting the synthesis "in situ" of nanoparticles in reverse micelles. In the case of aggregates containing copper ions, it is possible to form metallic particles surrounded or not by an oxide layer. By mixing aggregates containing cadmium and sulphide ions, CdS particles are formed. The size and polydispersity of the particles are controlled. The photoelectron transfer reaction depends mainly on the surface composition. In the range of 1 to 5 nm, the efficiency in the electron transfer does not depend on the size of the particle. The reverse micelles are formed by using either sodium di(2-ethyl hexyl)sulfosuccinate, usually called {AOT} or mixed bivalent and sodium di(2-ethyl hexyl)sulfosuccinate {AOT/M (AOT)2}.

Affiliations: 1: Université P. et M. Curie Laboratoire S.R.S.I. bâtiment F 4 Place Jussieu 75005 Paris, FRANCE, C.E.N. Saclay DRECAM.-S.C.M. 91191 Gif sur Yvette, FRANCE; 2: Université P. et M. Curie Laboratoire S.R.S.I. bâtiment F 4 Place Jussieu 75005 Paris, FRANCE; 3: C.E.N. Saclay DRECAM.-S.C.M. 91191 Gif sur Yvette, FRANCE

10.1163/156856792X00074
/content/journals/10.1163/156856792x00074
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/content/journals/10.1163/156856792x00074
2017-09-20

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