Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

1-Oxo-2,2,6,6-Tetramethyl-4-Chloropiperidinium Perchlorate. a New Facile Oxidant for Phenol Coupling

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

The title compound (1) oxidizes 2,6-di-tert-butylphenol (2), 2, 6-di-tert-butyl-4-methylphenol (3), 2,6-di-tert-butyl-4-(diphercylmethyl)phenol (4), and β-naphthol (5), to quinones in good yield under mild conditions in acetonitrile. For unsubstituted phenols the reaction takes place in two ways, phenol (6) is oxidized to quinhydrone (7), while the oxidation products of the phenols, α-naphthol, catechol and 2,4-dihydroxyl-naphthol were only polymers.

Affiliations: 1: Department of Chemistry Lanzhou University Lanzhou, Gansu 730000, CHINA


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation