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Platinum(Iii) Formation and Stabilization as "Platinum Blues" With Different Types of Ligands in the Course of Their Interaction With PtCl42- and cis-Pt(Nh3)2Cl2

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Studying the kinetics of PtCl42-, cis-[Pt(NH3)2(H2O)2]2+ and cis-Pt(NH3)2Cl2 (cis-DDP) reactions with different types of ligands using spectrophotometric, potentiometric and EPR methods, the conditions for Pt(III) formation as transient species and its further stabilization as 'Platinum Blue" complexes were found. A general method for obtaining 'Platinum Blue" species is suggested.

Affiliations: 1: Department of Chemistry University of Sofia 1126 Sofia, BULGARIA


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