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Non-Radiative Decay Rate of Vibrationally Excited Triplet Molecules

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The non-radiative decay rates of triplet benzene and 2-chloronaphthalene were determined as a function of excitation energy. As the excitation energies were increased, the non-radiative decay rates increased gradually. In the case of 2-chloronaphthalene it increased rapidly for the excitation energies above about 38000 cm-1.

Affiliations: 1: Department of Chemistry, Tokyo Institute of Technology, Ohokayama, Meguroku, Tokyo 152, JAPAN


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