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Novel Interactions of Radical-Ion Pairs: Cidep Studies of Photoionization and Photooxidation Reactions

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The time-resolved ESR studies of the photoionization of TMPD in alcohols showed the formation of a transient radical-ion pair and a solvated electron, where the positive sign of the exchange interaction was postulated. The addition of water to this system changed the spin-polarization pattern drastically. The photooxidation reaction of TMPD and N-ethylcarbazole with maleic anhydride (MA) in alcohols showed the TM (triplet mechanism)-like peculiar CIDEP. These phenomena were tentatively explained by the level crossing due to the Coulomb interaction of geminately formed radical-ion pairs.

Affiliations: 1: Department of Chemistry, Faculty of Science, Osaka University Toyonaka, Osaka 560, Japan


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