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Effect of Electron Transfer On the Geometry of Organic Compounds

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image of Research on Chemical Intermediates

The effect of the addition or the removal of an electron on the structure of organic substrates is discussed. Emphasis will be put on the information about the geometry of radical ions as obtained by EPR spectroscopy and on the use of simple computational tools such as Hückel MO theory and MM2 or INDO calculations in predicting the structural changes induced by ET processes.

Affiliations: 1: Dipartimento di Chimica Organica "A. Mangini", Università di Bologna, Via S. Donato 15, 1-40127 Bologna, Italy


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