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Electrochemical and Esr Studies of Aromatic Nitroso Spin Traps

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The oxidation and reduction potentials of 23 nitroso compounds among which were included the most important spin traps have been determined by means of cyclic voltammetry and voltammetry at the rotating electrode. The electron transfer generally involved one electron, leading to the corresponding ion radicals. When persistent species resulted from the electron transfer, their ESR spectra were recorded and analyzed with the help of EHT calculations. The observed anion radicals are typical delocalized Π radicals, while the cation radicals are Σ radicals with a SOMO orthogonal to the Π system. Secondary species formed from these primary ion radicals were also observed and identified by e.s.r.

Affiliations: 1: Laboratoire d'Electrochimie Organique et d'Instrumentation de l'ENSSPICAM, (CNRS URA 1410), Université d'Aix-Marseille , 13397 Marseille cedex 13, France; 2: Laboratoire de Structure et Réactivité des espèces paramagnétiques, (CNRS URA 1412), Université d'Aix-Marseille I, 13397 Marseille cedex 13, France

10.1163/156856793X00352
/content/journals/10.1163/156856793x00352
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/content/journals/10.1163/156856793x00352
1993-01-01
2016-12-09

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