Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Electrochemical and Esr Studies of Aromatic Nitroso Spin Traps

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

The oxidation and reduction potentials of 23 nitroso compounds among which were included the most important spin traps have been determined by means of cyclic voltammetry and voltammetry at the rotating electrode. The electron transfer generally involved one electron, leading to the corresponding ion radicals. When persistent species resulted from the electron transfer, their ESR spectra were recorded and analyzed with the help of EHT calculations. The observed anion radicals are typical delocalized Π radicals, while the cation radicals are Σ radicals with a SOMO orthogonal to the Π system. Secondary species formed from these primary ion radicals were also observed and identified by e.s.r.

Affiliations: 1: Laboratoire d'Electrochimie Organique et d'Instrumentation de l'ENSSPICAM, (CNRS URA 1410), Université d'Aix-Marseille , 13397 Marseille cedex 13, France; 2: Laboratoire de Structure et Réactivité des espèces paramagnétiques, (CNRS URA 1412), Université d'Aix-Marseille I, 13397 Marseille cedex 13, France


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation