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Progress of the Barton-McCombie Methodology: From Tin Hydrides To Silanes

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Use of organosilanes that promote the Barton-McCombie deoxygenation is an emerging methodology for organic transformations. A comparison between a variety of substituted silanes is presented. (Me3Si),SiH rivals Bu3SnH in efficiency and it is a superior reagent from ecological and practical perspectives.

Affiliations: 1: I.Co.CE.A., Consiglio Nazionale delle Ricerce, Via Gobetti 101, 1-40129 Bologna, Italy; 2: Dipartimento di Chimica Organica e Biologica, Università di Napoli, Via Mezzocannone 16, 1-80134 Napoli, Italy


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