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Time-Resolved Esr Study of Quasi-Stable Spin Correlated Radical Pairs in Sds Micellar Systems

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image of Research on Chemical Intermediates

Time-resolved ESR signals of quasi-stable spin correlated radical pairs were observed in the laser flash photolysis of xanthone and phenol derivatives in SDS micellar solutions. It was concluded that the fast population relaxation between two eigenstates of S and To occurs and the interaction of the spin correlated radical pair is preserved for a few μs in the micellar aggregate.

Affiliations: 1: Department of Chemistry, Faculty of Science, Osaka University, Toyonaka, Osaka 560, Japan


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