Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Self Quenching Reaction of (Phenoxymethyl)Chlorocarbene With Diazirine

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

The combination of laser flash photolysis and product analysis demonstrates that even though (phenoxymethyl)chlorocarbene reacts with its diazirine precursor with a substantial rate constant of 3.5 x 108 M-1 S-1, the predicted azine product is not formed. These results indicate either carbene/diazirine reversibility or subsequent hydrogen migration of the carbene/diazirine adduct. Also, a rate constant of 2.0 x 107 S-1 for the 1,2-hydrogen atom migration in (p-nitrophenoxymethyl)chlorocarbene has been determined using the pyridinium ylide technique.

Affiliations: 1: Department of Chemistry, University of Prince Edward Island, Charlottetown, Prince Edward Island Canada, C1A 4P3; 2: Radiation Laboratory, University of Notre Dame, Notre Dame, IN 46556, U.S.A.

10.1163/156856794X00199
/content/journals/10.1163/156856794x00199
dcterms_title,pub_keyword,dcterms_description,pub_author
10
5
Loading
Loading

Full text loading...

/content/journals/10.1163/156856794x00199
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/156856794x00199
Loading

Article metrics loading...

/content/journals/10.1163/156856794x00199
2017-09-25

Sign-in

Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation