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Properties of Excited States and One-Electron Reduced Forms of Ruthenium(Ii)-Diimine Photosensitizers

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In this paper we compare the spectral, acid-base, electrochemical, and kinetic properties of the excited states and one-electron reduced forms of homo- and heteroleptic Ru(II)-diimine photosensitizers that contain 2,2'-bipyridine, 2,2'-bipyrazine, and 2,2'-bipyrimidine ligands. These species, represented as *(RuIIIL.-)2+ and (RuIIL.-)+, respectively, are orbital analogues in that the intra- or intermolecularly transferred electron resides on the same uniquely reduced ligand. The variations in the properties of these species, resulting from changes in the coordinating ligands, permit the fine-tuning of photochemical systems.

Affiliations: 1: Department of Chemistry, Boston University, Boston, MA 02215, U.S.A.; 2: Istituto di Fotochimica e Radiazioni d'Alta Energia del CNR, 40126 Bologna, Italy


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