Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Properties of Excited States and One-Electron Reduced Forms of Ruthenium(Ii)-Diimine Photosensitizers

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

In this paper we compare the spectral, acid-base, electrochemical, and kinetic properties of the excited states and one-electron reduced forms of homo- and heteroleptic Ru(II)-diimine photosensitizers that contain 2,2'-bipyridine, 2,2'-bipyrazine, and 2,2'-bipyrimidine ligands. These species, represented as *(RuIIIL.-)2+ and (RuIIL.-)+, respectively, are orbital analogues in that the intra- or intermolecularly transferred electron resides on the same uniquely reduced ligand. The variations in the properties of these species, resulting from changes in the coordinating ligands, permit the fine-tuning of photochemical systems.

Affiliations: 1: Department of Chemistry, Boston University, Boston, MA 02215, U.S.A.; 2: Istituto di Fotochimica e Radiazioni d'Alta Energia del CNR, 40126 Bologna, Italy


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation