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ω-Hydro-Perfluoroalkyl Pyrimidinyl Nitroxides

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Twenty-two polysubstituted 2-aminopyrimidines dissolved in F113 (CC1F2-CCl2F) solutions containing {[H(CF2CF2)nCO2b n = 1,2} and H(CF2CF2)nNO [↔ H(CF2CF2)n* + NO] have been oxidized into detectable ω-H-perfluoroalkyl pyrimidinyl nitroxides along with neutral products. A mechanism involving H-abstraction from the amino groups by H(CF2CF2)nN(O*)(CF2CF2)nH and the subsequent radical steps was suggested for the generation of the nitroxides. Some relationships between aN values and the nature of the ring substituents are discussed.

Affiliations: 1: Department of Chemistry, Huazhong University of Science and Technology Wuhan 430074, China; 2: Department of Chemistry, Central China Normal University, Wuhan 430070, China


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