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Conformational Control in Previtamin d pHotochemistry By Heterogeneous Reaction Media

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The possibility of conformational control realization in the reaction of previtamin D photosynthesis in vitro was examined. The sharp changes in the kinetics of provitamin D photoisomerization in some heterogeneous media were attributed to the removal of previtamin D conformational equilibrium by the restriction of its intramolecular rotation. It was found that the quantitative evaluation of the reaction medium effect on the specific previtamin D reaction channels requires consideration of the irreversible photoconversions.

Affiliations: 1: Institute of Physics, Ukrainian Academy of Sciences, 252028, Kiev-28, Ukraine; 2: Institute of Surface Chemistry, Ukrainian Academy of Sciences, 252028, Kiev-28, Ukraine


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