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Photoacoustic Determination of Heats of Formation and Reaction of 5-Chloro-1,2-Didehydro-1H-Azepine, a Seven-Membered Cyclic Ketenimine

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The heats of formation and trapping by diethylamine of 5-chloro-1,2-didehydro-1H-azepine have been determined by time-resolved photoacoustic calorimetry (PAC). The results are compared with predictions from semiempirical calculations.

Affiliations: 1: Institut für Physikalische Chemie der Universität Basel,Klingelbergstrasse 80, CH-4056 Basel, Switzerland


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