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The Effect of Dark Recovery Time On the Photoefficiency of Heterogeneous Photocatalysis By TiO2 Suspended in Non-Aqueous Media

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Variation of dark recovery time influences the efficiency of a heterogeneous photocatalytic oxidation on irradiated TiO2 particles suspended in non-aqueous media, but does not affect the efficiency of a parallel photocatalyzed reduction. The efficiency of the photocatalyzed oxidation of 1-octanol on Degusa P-25 TiO2 in oxygenated acetonitrile nearly doubled when the dark interval between excitation pulses was increased from 0.1 s to 1 s. No improvement in photoefficiency could be detected in the photocatalytic reduction of p-nitroacetophenone under the same conditions.

Affiliations: 1: Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712, U.S.A

10.1163/156856795X00576
/content/journals/10.1163/156856795x00576
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/content/journals/10.1163/156856795x00576
1995-01-01
2016-12-04

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