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One-Way Isomerization and Internal Rotation in Anthrylethylenes in the Excited Triplet State

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image of Research on Chemical Intermediates

1-(2-Anthryl)-2-(bromophenyl)ethylene and 1-(2-anthryl)-2-(4-methoxyphenyl)ethylene undergo cis → trans one-way isomerization in the excited triplet state through an adiabatic process from the cis-triplet to the trans-triplet states. The trans-isomers of these compounds undergo one-way internal rotation in the excited triplet state with an activation barrier of ~7 kcal mol-1 and a frequency factor of ~1012 s-1, while no internal rotation takes place in the excited singlet state.

Affiliations: 1: Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305, Japan


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