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Detection of Radical Intermediates in the Photo-Oxidation of Alkanols By Ceric Ammonium Nitrate - Can. an Epr Study

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The photolysis of acetonitrile solutions of alkanols in the presence of ceric ammonium nitrate- CAN, at different temperatures, leads to the formation of alkyl, peroxyl and nitroxyl radicals identified by EPR spectroscopy. The involvement of free alkoxy and alkylperoxy radicals as intermediates in the reaction path will be discussed.

Affiliations: 1: Dipartimento di Chimica Organica "A. Mangini". Università di Bologna - Viale Risorgimento, 4 I-40136 Bologna, Italy

10.1163/156856796X00025
/content/journals/10.1163/156856796x00025
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/content/journals/10.1163/156856796x00025
1996-01-01
2016-12-06

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